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In an attempt to understand the complex interactions which
determine macroscopic characteristics of a substance, the project is
dedicated to determining the activation energies necessairy for
random, thermally-activated site jumps around molecular axes
of symetery. The magic angle spinning is used for
higher resolution and greater sensitivity in the experiments by
time averaging out the quadrupole interaction with the electric
field gradient. By performing these experiments on C8A and C20A
UIC, and after having a proper temperature calibration, a firm
support for the validity of the MAS approach can be established
by comparing the results with those from conventional static
experiments.
W. J. Kossler
2001-01-11